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Advances in enzyme bioelectrochemistry Anais da ABC (AABC)
PEREIRA,ANDRESSA R.; SEDENHO,GRAZIELA C.; SOUZA,JOÃO C. P. DE; CRESPILHO,FRANK N..
ABSTRACT Bioelectrochemistry can be defined as a branch of Chemical Science concerned with electron-proton transfer and transport involving biomolecules, as well as electrode reactions of redox enzymes. The bioelectrochemical reactions and system have direct impact in biotechnological development, in medical devices designing, in the behavior of DNA-protein complexes, in green-energy and bioenergy concepts, and make it possible an understanding of metabolism of all living organisms (e.g. humans) where biomolecules are integral to health and proper functioning. In the last years, many researchers have dedicated itself to study different redox enzymes by using electrochemistry, aiming to understand their mechanisms and to develop promising bioanodes and...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Bioelectrocatalysis; Biofuel cells; Bioelectrochemistry; Immobilization; Protein-electrode interactions; Redox enzymes.
Ano: 2018 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652018000200825
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Commemorative Volume on the Centenary of the Brazilian Academy of Sciences: “Brazil: Frontiers of Chemical Sciences” Anais da ABC (AABC)
CRESPILHO,FRANK N..
Tipo: Info:eu-repo/semantics/other
Ano: 2018 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652018000200591
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Dendritic Gold Nanoparticles Towards Transparent and Electroactive Electrodes Anais da ABC (AABC)
IOST,RODRIGO M.; MARTINS,MARCCUS V.A.; CRESPILHO,FRANK N..
Abstract: The combination of UV-visible absorption and electrochemical experiments (spectroelectrochemistry) enables to obtain highly specific spectroscopic information (in situ and operando) from modified surfaces. However, such application can be limited by the self-absorbance, for example, when metallic nanoparticles are present on modified surfaces. Indium-tin oxide onto glass (ITO) is a typical electrode commonly used for spectroelectrochemistry; ITO is an oxide-based semiconductor, and in numerous applications it is necessary to promote the modification of the electrode surface without significant loss of transparency. Here, we report a simple strategy to obtain ITO electrodes modified with self-assembled polyelectrolytes and active dendritic gold...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Indium tin oxide; Gold nanoparticles; Thin film; Electrodeposition.
Ano: 2019 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652019000700405
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